The halide-bridged cyclopalladated complexes [Pd2(m-X)2(k2-2-C6F4PPh2)2] (X = Cl, Br) were prepared in high yields from the reaction of equimolar amounts of 2-Me3SnC6F4PPh2 and [PdX2(cod)] (cod = 1,5-cyclooctadiene). These complexes are not thermodynamica
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